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Virial Equation for Monoatomic Molecules Derived from Canonical Partition Function
Virial Equation for Monoatomic Molecules Derived from Canonical Partition Function

Virial Equation for Monoatomic Molecules Derived from Canonical Partition Function

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Question:

Beginning with the canonical partition function,

use thermodynamics derivatives to derive the following "Pressure Equation" (also known as the Virial Equation) for monoatomic molecules:

State all assumptions that you make. Show all your work.
Hint: Use the pair wise additivity approximation.


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